Wiki:

Neal Caffrey, a con-man, forger and thief, is captured after a three-year game of cat and mouse with the FBI. With three months left while serving a four-year sentence, he escapes from a maximum-security federal prison to find Kate, his ex-girlfriend. Peter Burke, the FBI agent who initially captured Caffrey, finds him at a dead end in his search and returns Caffrey to prison. This time, Caffrey gives Burke information about evidence in another case; however, this information comes with a price: Burke must have a meeting with Caffrey. At this meeting, Caffrey proposes a deal: he will help Burke catch other criminals as part of a work-release program. Burke agrees, after some hesitation. Through the successful apprehending of several white-collar criminals, Caffrey has proven to Burke that he will help him, and that he will not try to escape again. This begins an unconventional, but successful partnership.

White Collar isn't as good as Psych or Castle...But maybe it'll turn out to be, I've watched only two episodes until now. But its pretty good, humor isn't bad. It isn't bad at all. ^^
Watch it, on Star World...its airing instead of Castle now. **nods**